2024 Acs macro letters - 100th Anniversary of Macromolecular Science Viewpoint: Re-Engineering Cellular Interfaces with Synthetic Macromolecules Using Metabolic Glycan Labeling. Ruben M. F. Tomás. and. Matthew I. Gibson *. ACS Macro Letters 2020, 9, 7, 991-1003 (Viewpoint) Publication Date (Web): June 25, 2020. Abstract. Full text.

 
ACS Macro Letters 2019, 8 (8) , 973-978. DOI: 10.1021/acsmacrolett.9b00439. Chang-Geun Chae, In-Gyu Bak, Jae-Suk Lee. Utilization of a Kinetic Principle of the Sequence-Controlled Anionic Copolymerization of Isocyanates toward Polyisocyanate Copolymers Encoded with Multiple Monomer Sequences. .... Acs macro letters

In today’s fast-paced business environment, efficiency is key. Every minute spent on repetitive and mundane tasks is a minute taken away from more important activities that could drive growth and innovation.When it gets far beyond the point of being white noise. Not only are window air conditioning units crucial for keeping cool during the hot summer months (at least for those who don’t have central AC), but they can also provide the soothing ...This study reveals the structural arrangements of polymers at the droplet interface, highlighting a notably more compact conformation at the interface compared to the interior of the droplet. These findings also extend to condensates formed by natural intrinsically disordered proteins. View the article.Get article recommendations from ACS based on references in your Mendeley library. You’ve supercharged your research process with ACS and Mendeley! ... ACS Macro Lett.Theory for the Elementary Time Scale of Stress Relaxation in Polymer Nanocomposites. Yuxing Zhou. Kenneth S. Schweizer*. ACS Macro Letters 2022, 11, 2, 199-204 (Letter) Publication Date (Web): January 15, 2022. Abstract.Mar 16, 2021 · Biofouling-Inspired Growth of Superhydrophilic Coating of Polyacrylic Acid on Hydrophobic Surfaces for Excellent Anti-Fouling. Tianyuan Han. , Zhuoyuan Ma. , and. Dayang Wang *. ACS Macro Letters 2021, 10, 3, 354-358 (Letter) Publication Date (Web): February 15, 2021. Abstract. A liquid drop may change its wettability on a surface with an applied voltage, known as electrowetting. Herein, we report an electrowetting phenomenon of a soft elastic gel, where gel elasticity plays an important role. We have designed experiments to measure the voltage-dependent adhesion energy between the gel and a metal electrode and proposed an electromechanical model for the ...RETURN TO ISSUE PREV Letter NEXT. Functionalizable, Side Chain-Immolative Poly(benzyl ether)s. Yue Xiao. ... Cite this: ACS Macro Lett. 2019, 8, 4, 399–402. Publication Date (Web): March 26, 2019. Publication History. Received 19 February 2019; Accepted 22 March 2019; Published online 26 March 2019;†Department of Chemistry and Biochemistry, University of Arizona, 1306 East University Boulevard, Tucson, Arizona 85721, United States § School of Chemical and Biological Engineering, The World Class University Program of Chemical Convergence for Energy and Environment, The National CRI Center for Intelligent Hybrids, and Center for …Nanoconfinement and Chemical Structure Effects on Permeation Selectivity of Self-Assembling Graft Copolymers. Chiara Vannucci. , Ikuo Taniguchi. , and. Ayse Asatekin *. ACS Macro Letters 2015, 4, 9, 872-878 (Letter) Publication Date (Web): August 6, 2015. Abstract.For those looking to become a bus driver, passing the class exams is an important part of the process. Bus driver class exams cover a variety of topics, from driving laws and regulations to safety procedures. Here are some tips for acing yo...ACS Macro Letters 2023, Article ASAP. Yang Ma, Ya-Nan Zhao, Xi-Man Yang, Jun-Fang Li, Xiao-Yan Wang, Yong Tang. SaBOX/Copper-Catalyzed Synthesis, Degradation, and Upcycling of a …Surface-initiated, Cu0-mediated ATRP demonstrates an efficient, oxygen-tolerant process to functionalize 3D microporous supports in a controlled fashion, forming single and multiple brush gradients with a fully tunable composition. View the article.Apr 21, 2020 · Theory of Spatial Gradients of Relaxation, Vitrification Temperature and Fragility of Glass-Forming Polymer Liquids Near Solid Substrates. Anh D. Phan *. and. Kenneth S. Schweizer *. ACS Macro Letters 2020, 9, 4, 448-453 (Letter) Publication Date (Web): March 13, 2020. Abstract.RETURN TO ARTICLES ASAP Letter NEXT. Autoxidation-Resistant, ROS-Scavenging, and Anti-Inflammatory Micellar Nanoparticles Self-Assembled from Poly(acrylic acid)–Green Tea Catechin Conjugates ... Cite this: …Mar 24, 2021 · In the past decade, photochemistry has emerged as a growing area in organic and polymer chemistry. Use of light to drive polymerization has advantages by imparting spatial and temporal control over the reaction. Photoinduced electron/energy transfer reversible addition–fragmentation chain transfer polymerization (PET-RAFT) has …This question is about the ACE Elite™ Visa® Prepaid Debit Card (Pay-As-You-Go) @lisacahill • 05/17/19 This answer was first published on 05/17/19. For the most current information about a financial product, you should always check and confi...RETURN TO ARTICLES ASAP Letter NEXT. Microgel-Modified Bilayered Hydrogels Dramatically Boosting Load-Bearing and Lubrication. Peng Lin * ... ACS Macro Lett. 2023, 12, XXX, 1450–1456. Publication Date (Web): October 16, 2023. Publication History. ... Get article recommendations from ACS based on references in your …Jun 30, 2023 · Download Hi-Res Image Download to MS-PowerPoint Cite This: ACS Macro Lett. 2023, XXXX, XXX, 974-979. ADVERTISEMENT. RETURN TO ARTICLES ASAP PREV Letter NEXT. Cancer remains a leading cause of death in many countries despite decades of research and innovative drug development. This virtual issue captures 2022 insights into cancer …100th Anniversary of Macromolecular Science Viewpoint: Re-Engineering Cellular Interfaces with Synthetic Macromolecules Using Metabolic Glycan Labeling. Ruben M. F. Tomás. and. Matthew I. Gibson *. ACS Macro Letters 2020, 9, 7, 991-1003 (Viewpoint) Publication Date (Web): June 25, 2020. Abstract. Full text.RETURN TO ARTICLES ASAP PREV Letter NEXT. Bridging the Monomer to Polymer Gap in Radical Polymer Design. Ying Tan. Ying Tan. ... Cite this: ACS Macro Lett. 2023, 12, XXX, 801–807. Publication Date (Web): May 31, 2023. Publication History. Received 20 February 2023; Accepted 25 May 2023;Surface coating is essential and critical to endow fiber materials with various functions for broad applications. However, it is still a great challenge to achieve a fast, fully covered, and robust surface coating on multiple fibers. In this work, a nanoscale surface coating with superior stability was rapidly and integrally formed on various fiber materials (such as Nylon mesh, nonwoven ...Jul 3, 2023 · Download Hi-Res Image Download to MS-PowerPoint Cite This: ACS Macro Lett. 2023, XXXX, XXX, 986-992. ADVERTISEMENT. RETURN TO ARTICLES ASAP Letter NEXT. Directional Self-Assembly of Nanoparticles Coated with Thermoresponsive Block Copolymers and Charged Small Molecules. Ga-Hyun Kim. Ga-Hyun Kim.ACS Macro Letters publishes research in all areas of contemporary soft matter science in which macromolecules play a key role, including nanotechnology, self-assembly, supramolecular chemistry, biomaterials, …Dec 5, 2022 · Polymer blend compatibilization is an attractive solution for mechanical recycling of mixed plastic waste because it can result in tough blends. In this work, hydroxy-telechelic polyethylene (HOPEOH) reactive additives were used to compatibilize blends of polyethylene terephthalate (PET) and linear low-density polyethylene (LLDPE). …Conjugated polymers (CPs) have been actively utilized as photocatalysts for hydrogen evolution due to their easy synthetic tunability to endow specific functionalities, including visible-light absorption, higher-lying LUMO energy for proton reduction, and sufficient photochemical stability. Enhancing interfacial surface and compatibility of hydrophobic CPs with hydrophilic water is the central ...Aug 13, 2022 · File Submission. Submit your own Manuscript PDF File—and provide your native LaTeX manuscript package as a ZIP archive. Compress the following into a single ZIP archive (.zip) file: Main body of the LaTeX document (i.e., a file ending with .tex or .ltx) All files referenced by the main LaTeX document (including other .tex files) Remember to ...16 កក្កដា 2019 ... 07/16/19: Wanting's paper is a cover image of ACS Macro Letters. Jae ... ACS Macro Lett. 8, 7, 806-811 (2019). © 2023 Nano-Engineering ...ACS Energy Letters, ACS Engineering Au, ACS Environmental Au, ACS ES&T Air, ACS ES&T ... ACS Macro Letters, ACS Materials Au, ACS Materials Letters, ACS ...Jun 2, 2022 · Poly(ethylene glycol) (PEG) has been extensively used in diverse applications. However, it is not biodegradable and shows abnormal immune responses. Herein, a fast, controlled, ring-opening polymerization (ROP) of 2-oxo-15-crown-5 (O-15C5) is reported to prepare well-defined PEG-like polyesters, poly(O-15C5). This approach relies on a …File Submission. Submit your own Manuscript PDF File—and provide your native LaTeX manuscript package as a ZIP archive. Compress the following into a single ZIP archive (.zip) file: Main body of the LaTeX document (i.e., a file ending with .tex or .ltx) All files referenced by the main LaTeX document (including other .tex files) Remember to ...Oct 25, 2023 · ACS Macro Letters welcomes submissions in all areas of contemporary soft matter science in which macromolecules play a key role, including nanotechnology, self-assembly, supramolecular chemistry, biomaterials and biomedical materials, membranes and separations, energy generation and storage, and renewable/sustainable materials. ACS Macro Letters 2020, 9, 1, 123-133 (Viewpoint) Publication Date (Web): January 8, 2020 Abstract Full text PDF ABSTRACT Letters Multiaxial Stress Relaxation of Dual-Cross-Link Poly (vinyl alcohol) Hydrogels Takuro Kimura and Kenji Urayama * ACS Macro Letters 2020, 9, 1, 1-6 (Letter)Are you a military aspirant looking to ace the Armed Services Vocational Aptitude Battery (ASVAB) test? If yes, then you’ve come to the right place. The ASVAB is a comprehensive test that measures your aptitude in ten different areas.This study reveals the structural arrangements of polymers at the droplet interface, highlighting a notably more compact conformation at the interface compared to the …If you own a Robinair AC machine, you know how important it is to keep it in good working order. One of the key components of your machine is the wiring system. Without proper wiring, your machine won’t function as it should.Are you a military aspirant looking to ace the Armed Services Vocational Aptitude Battery (ASVAB) test? If yes, then you’ve come to the right place. The ASVAB is a comprehensive test that measures your aptitude in ten different areas.Please reconnect. We demonstrate waterborne, unimolecularly dissolved vitrimer prepolymer systems that can be transferred into a vitrimer material using catalytic transesterification. The one-component prepolymer system can be processed via film casting and subsequent heat-induced cross-linking. A variation of the density of side …Van der Waals-driven self-healing in copolymers with “lock-and-key” architecture has emerged as a concept to endow engineering-type polymers with the capacity to recover from structural damage. Complicating the realization of “lock-and-key”-enabled self-healing is the tendency of copolymers to form nonuniform sequence distributions during polymerization reactions. This limits favorable ...Weak mechanical properties and excessive swelling due to high water content in hydrogels are two of the biggest challenges for their development in the field of bioelectronics. As an alternative, proposed diazirine-based hydrophobic CaproGlu adhesives can adhere to soft tissues, mimic tissue mechanical properties, cross-link in the presence of water, and provide electrical conductivity and ... Poly(vinyl phosphonic acid)-based double hydrophilic block copolymers by gadolinium ions are demonstrated to be the polymer of choice in the design of highly stable MRI contrast agents. Measurement of high magnetic relaxivities in vitro and in vivo magnetic resonance imaging on rats demonstrate the high potential of such polymeric assemblies. …... ACS Macro Letters/ Biomacromolecules/ Macromolecules Young Investigators Award. Sponsored by ACS Macro Letters , Biomacromolecules , and Macromolecules along ...Jun 21, 2023 · Cellulose-based dielectrics with attractive dielectric performance are promising candidates to develop eco-friendly electrostatic energy storage devices. Herein, all-cellulose composite films with superior dielectric constant were fabricated by manipulating the dissolution temperature of native cellulose, where we revealed the relationship among the hierarchical microstructure of the ... The results showed that these UCST-type microcages behaved with the appropriate phase-transition threshold value around 40 °C, and spontaneously underwent an expansion–fusion–fission cycle under the stimulus of mild temperature hyperthermia. Given the simultaneous local release of cargoes, this simple but smart microcage is expected …ACS Macro Letters has been certified as a transformative journal by cOAlition S, committing to a transition to 100% open access in the future. If your research funder has signed Plan S, your open access charges may be covered by your funder through December 31, 2024. Please visit the ACS Open Science website for more information.Antibacterial polypeptides as ancient immune defense systems are effective against bacteria. Here we report a novel kind of “armed” carrier: an antibacterial polypeptide-grafted chitosan-based nanocapsule with an excellent antibacterial efficacy against both Gram-positive and Gram-negative bacteria. This nanocapsule also has excellent blood …The origin of the activated monomer mechanism (AMM) in cationic ring-opening polymerization (CROP) is described first. Then, conditions leading to the active chain end (ACE) mechanism and AMM are compared, as well as methods allowing to distinguish between these two mechanisms. These methods are based on the “ion trapping” of the active ionic species using highly basic phosphines or by ...Download Hi-Res Image Download to MS-PowerPoint Cite This: ACS Macro Lett. 2019, 8, 4, 399-402. ADVERTISEMENT. RETURN TO ISSUE PREV Letter NEXT. Functionalizable, Side Chain-Immolative Poly(benzyl ether)s. Yue Xiao. Yue Xiao. Institute of Chemical Biology and Nanomedicine, College of Chemistry and Chemical Engineering, Hunan …... ACS Engineering Au, ACS Environmental Au, ACS ES&T Air, ACS ES&T Engineering, ACS ES&T Water, ACS Food Science & Technology, ACS Infectious Diseases, ACS Macro ...We investigate the dynamics of polymers grafted to spherical nanoparticles in solution using hybrid molecular dynamics simulations with a coarse-grained solvent modeled via the multiparticle collision dynamics algorithm. The mean-square displacements of monomers near the surface of the nanoparticle exhibit a plateau on intermediate time scales, …3 កុម្ភៈ 2014 ... ... ACS Macro Letters. The three-year term began January 1, 2014. As a member of the Editorial Advisory Board, Li works with the ACS ...This question is about the ACE Elite™ Visa® Prepaid Debit Card (Pay-As-You-Go) @lisacahill • 05/17/19 This answer was first published on 05/17/19. For the most current information about a financial product, you should always check and confi...RETURN TO ISSUE PREV Letter NEXT. Mechanisms of Degradation for Polydisulfides: Main Chain Scission, Self-Immolation, Or Chain Transfer Depolymerization. ... Cite this: ACS Macro Lett. 2023, 12, 7, 955–960. Publication Date (Web): June 29, 2023. Publication History. Received 1 June 2023; Accepted 26 June 2023;Dispersity (Đ) as a critical parameter indicates the level of uniformity of the polymer molar mass or chain length. In the past several decades, the development of explicit equations for calculating Đ experiences a continual revolution. This viewpoint tracks the historical evolution of the explicit equations from living to reversible-deactivation …Mar 28, 2023 · The conventional hydration number, λ, of a polymer electrolyte membrane (PEM) is estimated by the gravimetric measurement of the total water uptake in the membrane. This is the overall water molecules divided by the number of ionic groups covering the water distribution from the macroscale to the molecular level. For a more precise evaluation of the local ion–water interactions and ion ... 3 កុម្ភៈ 2014 ... ... ACS Macro Letters. The three-year term began January 1, 2014. As a member of the Editorial Advisory Board, Li works with the ACS ...Sep 15, 2023 · Side substitution is an effective method for the chemical modification and functionalization of linear polyesters. The presence of side groups can have a profound effect on the crystalline structure and phase transition of semicrystalline polyesters. Herein, we synthesized the long-spaced polyesters with −OH and −CH3 side groups and various methylene segment lengths and studied the effects ... The origin of the activated monomer mechanism (AMM) in cationic ring-opening polymerization (CROP) is described first. Then, conditions leading to the active chain end (ACE) mechanism and AMM are compared, as well as methods allowing to distinguish between these two mechanisms. These methods are based on the “ion trapping” of the …Poly(vinyl phosphonic acid)-based double hydrophilic block copolymers by gadolinium ions are demonstrated to be the polymer of choice in the design of highly stable MRI contrast agents. Measurement of high magnetic relaxivities in vitro and in vivo magnetic resonance imaging on rats demonstrate the high potential of such polymeric assemblies. …Reaction Environment Effect on the Kinetics of Radical Thiol–Ene Polymerizations in the Presence of Amines and Thiolate Anions. Dillon Love. , Benjamin Fairbanks. , and. Christopher Bowman *. ACS Macro Letters 2020, 9, 2, 174-179 (Letter) Publication Date (Web): January 16, 2020. Abstract.Light-mediated radical polymerization has benefited from the rapid development of photoredox catalysts and offers many exceptional advantages over traditional thermal polymerizations. Nevertheless, the majority of the work relies on molecular photoredox catalysts or expensive transition metals. We exploited the capability of semiconductor quantum dots (QD) as a new type of catalyst for the ...Correlation between Self-Folding Behavior of Amphiphilic Polymers and Their Molecular Flexibility. Masanori Nagao *. and. Yoshiko Miura *. ACS Macro Letters 2023, 12, 6, 733-737 (Letter) Publication Date (Web): …Mar 27, 2023 · Van der Waals-driven self-healing in copolymers with “lock-and-key” architecture has emerged as a concept to endow engineering-type polymers with the capacity to recover from structural damage. Complicating the realization of “lock-and-key”-enabled self-healing is the tendency of copolymers to form nonuniform sequence …The origin of the activated monomer mechanism (AMM) in cationic ring-opening polymerization (CROP) is described first. Then, conditions leading to the active chain end (ACE) mechanism and AMM are compared, as well as methods allowing to distinguish between these two mechanisms. These methods are based on the “ion trapping” of the active ionic species using highly basic phosphines or by ...Aug 13, 2022 · File Submission. Submit your own Manuscript PDF File—and provide your native LaTeX manuscript package as a ZIP archive. Compress the following into a single ZIP archive (.zip) file: Main body of the LaTeX document (i.e., a file ending with .tex or .ltx) All files referenced by the main LaTeX document (including other .tex files) Remember to ...Stereoselective copolymerization of vinyl ethers using a chiral BINOL-based phosphoric acid in combination with a titanium Lewis acid enabled the realization of semicrystalline thermoplastics with tunable thermomechanical properties. The broad substrate scope of the catalyst facilitated the copolymerization of structurally diverse monomers without sacrificing stereoselectivity. The method ...Rapid, solvent-free synthesis of poly(1,4-butadiene) in ambient conditions is demonstrated by frontal ring-opening metathesis polymerization (FROMP) of 1,5-cyclooctadiene (COD). Furthermore, cross-linked copolymers with a wide range of tunable properties are readily prepared by FROMP of mixtures of COD and dicyclopentadiene …Jun 8, 2023 · Abstract. A liquid drop may change its wettability on a surface with an applied voltage, known as electrowetting. Herein, we report an electrowetting phenomenon of a soft elastic gel, where gel elasticity plays an important role. We have designed experiments to measure the voltage-dependent adhesion energy between the gel and a metal electrode ... Jul 3, 2023 · Download Hi-Res Image Download to MS-PowerPoint Cite This: ACS Macro Lett. 2023, XXXX, XXX, 986-992. ADVERTISEMENT. RETURN TO ARTICLES ASAP Letter NEXT. Jun 30, 2023 · Download Hi-Res Image Download to MS-PowerPoint Cite This: ACS Macro Lett. 2023, XXXX, XXX, 974-979. ADVERTISEMENT. RETURN TO ARTICLES ASAP PREV Letter NEXT. Jun 8, 2023 · Abstract. A liquid drop may change its wettability on a surface with an applied voltage, known as electrowetting. Herein, we report an electrowetting phenomenon of a soft elastic gel, where gel elasticity plays an important role. We have designed experiments to measure the voltage-dependent adhesion energy between the gel and a metal electrode ... Abstract. A novel type of fluorescence without large conjugated structures called clusteroluminescence (CL) has attracted a great deal of attention in recent years. …ACS Macro Letters has been certified as a transformative journal by cOAlition S, committing to a transition to 100% open access in the future. If your research funder has signed Plan S, your open access charges may be covered by your funder through December 31, 2024. Please visit the ACS Open Science website for more information.Get article recommendations from ACS based on references in your Mendeley library. You’ve supercharged your research process with ACS and Mendeley! ... ACS Macro Lett.100th Anniversary of Macromolecular Science Viewpoint: Re-Engineering Cellular Interfaces with Synthetic Macromolecules Using Metabolic Glycan Labeling. Ruben M. F. Tomás. and. Matthew I. Gibson *. ACS Macro Letters 2020, 9, 7, 991-1003 (Viewpoint) Publication Date (Web): June 25, 2020. Abstract. Full text.ACS Macro Letters publishes research in all areas of contemporary soft matter science in which macromolecules play a key role, including nanotechnology, self-assembly, supramolecular chemistry, biomaterials, energy generation and storage, and renewable/sustainable materials.Supramolecular polymers (SPs) formed by self-assembly of peptide-based molecular units assume a variety of interesting one-dimensional (1D) morphologies. While the morphological complexity and phase behavior of self-assembling peptide conjugates bear some resemblance to those of low-molecular-weight and macromolecular surfactants, Y-junctions, or three-way connected constructs, a topological ...A library of fluorinated aryl diazomethanes were polymerized using BF3·OEt2 as a catalyst. The polymerization of 2,3,4,5,6-pentafluorophenyl diazomethane was found to be controlled, permitted chain extensions, and facilitated access to a series of block copolymers. Moreover, the polymer chains grew in one carbon increments (so …If you own a Robinair AC machine, you know how important it is to keep it in good working order. One of the key components of your machine is the wiring system. Without proper wiring, your machine won’t function as it should., Youshen Wu , Zhishen Ge , Yilong Cheng , and Yanfeng Zhang * ACS Macro Letters 2023, 12, 5, 543-548 (Letter) Publication Date (Web): April 11, 2023 Abstract Full text PDF ABSTRACT Nonlinear Viscoelasticity and Toughening Mechanisms in Nanoclay-PNIPAAm Double Network Hydrogels Lin Xu * , Samuel C. Lamont Download Hi-Res Image Download to MS-PowerPoint Cite This: ACS Macro Lett. 2019, 8, 11, 1522-1527. ADVERTISEMENT. Wednesday, June 7. We are undergoing maintenance which may impact PDF downloads for some users. This update will complete shortly and we appreciate your patience while we improve the ACS Publications Platform. ... ACS …Authors who submit Letters are encouraged but not required to use one of the templates available below. Use of the template will ensure proper formatting and will facilitate the placement of graphics in the manuscript. It will allow authors and editors to accurately estimate the length of Letters at submission and will eliminate any delay ... Photoreversible Order–Disorder Transition in an Ionic Liquid Solvated Block Polymer. Cecilia C. Hall. and. Timothy P. Lodge *. ACS Macro Letters 2019, 8, 4, 393-398 (Letter) Publication Date (Web): March 26, 2019. Abstract. Surface-initiated, Cu0-mediated ATRP demonstrates an efficient, oxygen-tolerant process to functionalize 3D microporous supports in a controlled fashion, forming single and multiple brush gradients with a fully tunable composition. View the article.Apr 20, 2021 · Issue Publication Information. ACS Macro Letters 2021, 10, 4, XXX-XXX (Article) Publication Date (Web): April 20, 2021. PDF. Data-driven models trained to learn a predictive map between protein sequence and function can efficiently navigate protein sequence space to prospectively identify proteins with improved or novel function. Acs macro letters

Download Hi-Res Image Download to MS-PowerPoint Cite This: ACS Macro Lett. 2023, XXXX, XXX, 974-979. ADVERTISEMENT. RETURN TO ARTICLES ASAP PREV Letter NEXT.. Acs macro letters

acs macro letters

ACS Macro Letters published several important papers on novel synthesis of naturally derived synthetic polysaccharides and glycopolymers. For example, Grinstaff and his colleagues have published a number of ACS Macro Letters on their polyamidosaccharides (PASs) over the years. PAS is a type of naturally derived synthetic polysaccharide, made ...Ensure that any symbols and abbreviations used in the text agree with those in the artwork. Authors are required to ensure that similar figures have similar resolution and quality (all black and white figures should have resolution similar to each other; all color figures should have resolution similar to each other).While much research has been aimed at new approaches to the healing of cross-linked polymers, there is a dearth of effort in the healing of renewable cross-linked polymers. In this study, the healing ability of renewable polylactide-based vitrimers containing Sn(Oct)2 was investigated. The vitrimers were prepared from hydroxyl-terminated star-shaped poly((±) …Stereoselective copolymerization of vinyl ethers using a chiral BINOL-based phosphoric acid in combination with a titanium Lewis acid enabled the realization of semicrystalline thermoplastics with tunable thermomechanical properties. The broad substrate scope of the catalyst facilitated the copolymerization of structurally diverse monomers without sacrificing stereoselectivity. The method ...Ohio Electric Motors indicates that the main difference between AC and DC motors is the power source. AC motors are powered by an alternating current while DC motors use a direct current as a power source.ACS Macro Letters is a journal published by American Chemical Society.This journal covers the area[s] related to Inorganic Chemistry, Materials Chemistry, Organic Chemistry, Polymers and Plastics, etc.The coverage history of this journal is as follows: 2012-2022. The rank of this journal is 1796.This journal's impact score, h-index, …Dynamic covalent bonds can be incorporated into polymer networks for a host of applications. In this Viewpoint, Evans and coworkers describe the outlook for this class of polymers and highlight key questions regarding how dynamic bonds impact self-assembly, viscoelasticity, and functionality of dynamic polymer networks. View the article.Theory of Spatial Gradients of Relaxation, Vitrification Temperature and Fragility of Glass-Forming Polymer Liquids Near Solid Substrates. Anh D. Phan *. and. Kenneth S. Schweizer *. ACS Macro Letters 2020, 9, 4, 448-453 (Letter) Publication Date (Web): March 13, 2020. Abstract.Herein we report a novel family of deep eutectic monomers and the corresponding polymers, made of (meth)acrylic ammonium salts and a series of biobased polyphenols bearing catechol or pyrogallol motifs. Phenolic chemistry allows modulating molecular interactions by tuning the ionic polymer properties from soft adhesive to tough …The origin of the activated monomer mechanism (AMM) in cationic ring-opening polymerization (CROP) is described first. Then, conditions leading to the active chain end (ACE) mechanism and AMM are compared, as well as methods allowing to distinguish between these two mechanisms. These methods are based on the “ion trapping” of the active ionic species using highly basic phosphines or by ...Oct 25, 2023 · Ensure that any symbols and abbreviations used in the text agree with those in the artwork. Authors are required to ensure that similar figures have similar resolution and quality (all black and white figures should have resolution similar to each other; all color figures should have resolution similar to each other). 100th Anniversary of Macromolecular Science Viewpoint: Re-Engineering Cellular Interfaces with Synthetic Macromolecules Using Metabolic Glycan Labeling. Ruben M. F. Tomás. and. Matthew I. Gibson *. ACS Macro Letters 2020, 9, 7, 991-1003 (Viewpoint) Publication Date (Web): June 25, 2020. Abstract. Full text.Dual organocatalysts based on ionic mixtures of acids and bases have become a powerful tool in high temperature (de)polymerization reactions, owing to their easy synthesis, versatility, catalytic properties, and thermal stability. Image courtesy of Andere Basterretxea, Coralie Jehanno, David Mecerreyes, and Haritz Sardon. View the article. ACS macro letters (2020), 9 (4), 476-493 ISSN:. Sustainable polymers from lignocellulosic biomass have the potential to reduce the environmental impact of commercial plastics while also offering significant performance and cost benefits relative to petrochemical-derived macromolecules.Poly(methyl methacrylate/n-butyl acrylate) [P(MMA/BA)] copolymer with an alternating structure was synthesized via an activator regenerated by electron transfer (ARGET) atom transfer radical (co)polymerization (ATRP) of 2-ethylfenchyl methacrylate (EFMA) and n-butyl acrylate (BA) with subsequent postpolymerization modifications (PPM). Due to the steric hindrance of the bulky pendant group of ...Apr 21, 2020 · Theory of Spatial Gradients of Relaxation, Vitrification Temperature and Fragility of Glass-Forming Polymer Liquids Near Solid Substrates. Anh D. Phan *. and. Kenneth S. Schweizer *. ACS Macro Letters 2020, 9, 4, 448-453 (Letter) Publication Date (Web): March 13, 2020. Abstract. In the past decade, photochemistry has emerged as a growing area in organic and polymer chemistry. Use of light to drive polymerization has advantages by imparting spatial and temporal control over the reaction. Photoinduced electron/energy transfer reversible addition–fragmentation chain transfer polymerization (PET-RAFT) has emerged as an excellent technique for developing well-defined ...Feb 1, 2019 · Aqueous emulsion polymerization is one of the most commonly used techniques in industry for the production of polymer latexes. In this contribution, we present photoinitiated polymerization-induced self-assembly (photo-PISA) based on aqueous visible light-induced reversible addition–fragmentation chain transfer (RAFT)-mediated emulsion …Optical Tweezers Microrheology: From the Basics to Advanced Techniques and Applications. Rae M. Robertson-Anderson *. ACS Macro Letters 2018, 7, 8, 968-975 (Viewpoint) Publication Date (Web): August 5, 2018. Abstract.RETURN TO ISSUE PREV Letter NEXT. Functionalizable, Side Chain-Immolative Poly(benzyl ether)s. Yue Xiao. ... Cite this: ACS Macro Lett. 2019, 8, 4, 399–402. Publication Date (Web): March 26, 2019. Publication History. Received 19 February 2019; Accepted 22 March 2019; Published online 26 March 2019;Recent advances in nanotechnologies have promoted the iterative updating of nucleic acid sensors. Among various sensing technologies, the electrical nanobiosensor is regarded as one of the most promising prospects to achieve rapid, precise, and point-of-care nucleic acid based diagnostics. In this Perspective, we introduce recent progresses in …Aug 13, 2022 · File Submission. Submit your own Manuscript PDF File—and provide your native LaTeX manuscript package as a ZIP archive. Compress the following into a single ZIP archive (.zip) file: Main body of the LaTeX document (i.e., a file ending with .tex or .ltx) All files referenced by the main LaTeX document (including other .tex files) Remember to ...Submissions to ACS Macro Letters should justify clearly the rapid disclosure of the key elements of the study in both the cover letter and the manuscript. For more details, visit the journal website. Manuscript Types ACS Macro Letters is an online publication and predominantly publishes research Letters. The journal also publishes Viewpoints ...The inherent statistical heterogeneities associated with chain length, composition, and architecture of synthetic block copolymers compromise the quantitative interpretation of their self-assembly process. This study scrutinizes the contribution of molecular architecture on phase behaviors using discrete ABA triblock copolymers with …Feb 8, 2023 · Specific neoantigens are promising candidates for personalized cancer vaccines and immunotherapies, whereas the low immunogenicity and physicochemical variability are the main challenges in clinical trials. Herein, based on the rational design of neoantigens, we developed biepitope nanovaccines via integrating CD4+ with CD8+ T …RETURN TO ISSUE PREV Letter NEXT. Functionalizable, Side Chain-Immolative Poly(benzyl ether)s. Yue Xiao. ... Cite this: ACS Macro Lett. 2019, 8, 4, 399–402. Publication Date (Web): March 26, 2019. Publication History. Received 19 February 2019; Accepted 22 March 2019; Published online 26 March 2019;Apr 11, 2023 · Multicomponent polymerization (MCP) has the advantages of high efficiency, mild reaction conditions, and high yield and has been widely used to synthesize multifunctional polymers. In this report, we develop novel covalent adaptable networks (CANs) with dynamic thioaminal covalent bonds via a simple one-pot thiol–aldehyde–amine MCP. The dynamic behaviors of the thioaminal group are ... Oct 25, 2023 · Submissions to ACS Macro Letters should justify clearly the rapid disclosure of the key elements of the study in both the cover letter and the manuscript. For more details, visit the journal website. Manuscript Types ACS Macro Letters is an online publication and predominantly publishes research Letters. The journal also publishes …How can single-chain polymer nanoparticles (SCNPs) be used to manipulate the mechanical properties of polymer networks? This article reports a novel approach to create multi-stimuli-responsive hydrogels by cross-linking SCNPs with dynamic covalent bonds. The resulting materials exhibit tunable elasticity, self-healing, and shape memory behaviors. Read more to learn about the synthesis ...Stimuli-responsive opposite emission (A)/absorption (B) polymer material (A∪B = Ω and A∩B = Ø) represents a novel polymer material that is difficult to prepare. Here, we demonstrate a one-pot strategy for the molecular design of stimuli-responsive opposite emission/absorption polymer material with intriguing properties of opposite emission/absorption and aggregation-induced emission (AIE ...Weak mechanical properties and excessive swelling due to high water content in hydrogels are two of the biggest challenges for their development in the field of bioelectronics. As an alternative, proposed diazirine-based hydrophobic CaproGlu adhesives can adhere to soft tissues, mimic tissue mechanical properties, cross-link in the presence of water, and provide electrical conductivity and ... In today’s competitive job market, standing out from the crowd is essential. While many job seekers focus solely on crafting the perfect resume and acing the interview, they often overlook a crucial step in the post-interview process – send...†Department of Chemistry and Biochemistry, University of Arizona, 1306 East University Boulevard, Tucson, Arizona 85721, United States § School of Chemical and Biological Engineering, The World Class University Program of Chemical Convergence for Energy and Environment, The National CRI Center for Intelligent Hybrids, and Center for …ACS Macro Letters (2020), 9 (7), 1040-1045 CODEN: AMLCCD; ISSN: 2161-1653. ( American Chemical Society ) An original route to develop an advanced class of microgel emulsifiers contg. stimulable metallo-supramol. instead of frozen covalent cross-links is reported.RETURN TO ISSUE PREV Letter NEXT. Functionalizable, Side Chain-Immolative Poly(benzyl ether)s. Yue Xiao. ... Cite this: ACS Macro Lett. 2019, 8, 4, 399–402. Publication Date (Web): March 26, 2019. Publication History. Received 19 February 2019; Accepted 22 March 2019; Published online 26 March 2019;Bilayer hydrogels encoded with smart functions have emerged as promising soft materials for engineered biological tissues and human-machine interfaces, due to the versatility and flexibility in designing their mechanical and chemical properties. However, conventional fabrication strategies often require multiple complicated steps to create an anisotropic bilayer structure with poor interfaces ... This study compares the scattering signatures of two polymer electrolytes (PPM/TFSI and PEO/TFSI). The combination of X-ray scattering and computer simulation provides a powerful tool to accurately identify and understand the ion solvation structure. View the article.Melting of crystals is an archetypical first order phase transition. Albeit extensive efforts, the molecular origin of this process in polymers is still not clear. Experiments are complicated by the tremendous change in mechanical properties and the occurrence of parasitic phenomena masking the genuine material response. Here, we present an experimental …Polymer-topology effects can alter technologically relevant properties when cyclic macromolecules are applied within diverse materials formulations. These include coatings, polymer networks, or nanostructures for delivering therapeutics. While substituting linear building blocks with cyclic analogues in commonly studied materials is itself of fundamental interest, an even more fascinating ...Recent advances in nanotechnologies have promoted the iterative updating of nucleic acid sensors. Among various sensing technologies, the electrical nanobiosensor is regarded as one of the most promising prospects to achieve rapid, precise, and point-of-care nucleic acid based diagnostics. In this Perspective, we introduce recent progresses in …Are you looking to become a certified professional coder (CPC)? If so, you’ll need to pass the CPC practice exam. Taking the practice exam is a great way to prepare for the real thing and increase your chances of passing. Here’s your ultima...When it comes to cooling your home, there are several options available in the market. Two of the most popular types of air conditioners are portable ACs and window ACs. In this article, we will compare portable ACs and window ACs and help ...Polymer blend compatibilization is an attractive solution for mechanical recycling of mixed plastic waste because it can result in tough blends. In this work, hydroxy-telechelic polyethylene (HOPEOH) reactive additives were used to compatibilize blends of polyethylene terephthalate (PET) and linear low-density polyethylene (LLDPE). …Abstract. A liquid drop may change its wettability on a surface with an applied voltage, known as electrowetting. Herein, we report an electrowetting phenomenon of a soft elastic gel, where gel elasticity …Jun 8, 2023 · Abstract. A liquid drop may change its wettability on a surface with an applied voltage, known as electrowetting. Herein, we report an electrowetting phenomenon of a soft elastic gel, where gel elasticity plays an important role. We have designed experiments to measure the voltage-dependent adhesion energy between the gel and a metal electrode ... RETURN TO ISSUE PREV Letter NEXT. Nanovaccine Based on a Biepitope Antigen to Potentiate the Immunogenicity of a Neoantigen. Shuyu Chen. Shuyu Chen. ... Cite this: ACS Macro Lett. 2023, 12, 2, 281–287. Publication Date (Web): February 8, 2023. Publication History. Received 18 December 2022;The results showed that these UCST-type microcages behaved with the appropriate phase-transition threshold value around 40 °C, and spontaneously underwent an expansion–fusion–fission cycle under the stimulus of mild temperature hyperthermia. Given the simultaneous local release of cargoes, this simple but smart microcage is expected to act ...DOI: 10.1021/acs.macromol.9b01275. Yi Wang, Liye Fu, Krzysztof Matyjaszewski. Enzyme-Deoxygenated Low Parts per Million Atom Transfer Radical Polymerization in Miniemulsion and Ab Initio Emulsion. ACS Macro Letters 2018, 7 (11) , 1317-1321. DOI: 10.1021/acsmacrolett.8b00711.Jul 3, 2023 · Download Hi-Res Image Download to MS-PowerPoint Cite This: ACS Macro Lett. 2023, XXXX, XXX, 986-992. ADVERTISEMENT. RETURN TO ARTICLES ASAP Letter NEXT. Oligothiophene derivatives self-assemble into nanofibrils with a helically twisted core embedded into a soft shell of the terminally attached flexible polyisoprene segments. The …Dual organocatalysts based on ionic mixtures of acids and bases have become a powerful tool in high temperature (de)polymerization reactions, owing to their easy synthesis, versatility, catalytic properties, and thermal stability. Image courtesy of Andere Basterretxea, Coralie Jehanno, David Mecerreyes, and Haritz Sardon. View the article.RETURN TO ARTICLES ASAP Letter NEXT. Dynamic Cross-Linked Polyethylene Networks with High Energy Storage and Electrical Damage Self-Healability. Zhen Li. Zhen Li. ... Cite this: ACS Macro Lett. 2023, 12, XXX, 1409–1415. Publication Date (Web): October 4, 2023. Publication History. Received 2 July 2023; Accepted 25 …Oct 29, 2018 · Abstract. Spider silk exhibits a combination of outstanding tensile strength and extensibility unique among all synthetic and biogenic polymer fibers. It has thus generated great interest to understand protein-based high-toughness materials and inspired the design of similar synthetic materials. The unrivaled properties of silk fibers have been ... The ability to perform solute-specific separations has transformative potential for water treatment processes. Advanced polymer membrane synthesis using chemistries tailored for individual molecules, alongside fundamental studies from the broad polymer science community, could facilitate design of such systems. Cover art designer: Joshua D. Moon View the article. Understanding the physicochemical properties of hydrogel surfaces and their molecular origins is important for their applications. In this paper, we elucidate the molecular origin of surface charges in double-network hydrogels synthesized by two-step sequential polymerization. Synthesis of hydrogels by free-radical polymerization does not fully complete the reaction, leaving a small number of ...How can single-chain polymer nanoparticles (SCNPs) be used to manipulate the mechanical properties of polymer networks? This article reports a novel approach to create multi-stimuli-responsive hydrogels by cross-linking SCNPs with dynamic covalent bonds. The resulting materials exhibit tunable elasticity, self-healing, and shape memory behaviors. Read more to learn about the synthesis ...Dual organocatalysts based on ionic mixtures of acids and bases have become a powerful tool in high temperature (de)polymerization reactions, owing to their easy synthesis, versatility, catalytic properties, and thermal stability. Image courtesy of Andere Basterretxea, Coralie Jehanno, David Mecerreyes, and Haritz Sardon. View the article.In today’s competitive job market, standing out from the crowd is essential. While many job seekers focus solely on crafting the perfect resume and acing the interview, they often overlook a crucial step in the post-interview process – send...Feb 15, 2022 · A twinflower is thriving in the grassland of a polymer synthesis. This catalyst-free and visible light-induced step-growth polymerization method was developed by employing a photo-RAFT single unit monomer insertion reaction. A pendent cationic RAFT agent was formed in each repeat unit of the backbone, which could be used for both radical and cationic chain extensions to produce different ... The study of mechanoresponsive properties of nanovesicles is essential to understand and regulate many physiological activities. The actual capillary number-dependent force-responsive performance of vesicles was revealed unprecedentedly at the nanoscale level. Polydiacetylene was found as a sensitive chromic mechanoresponsive …The ability to perform solute-specific separations has transformative potential for water treatment processes. Advanced polymer membrane synthesis using chemistries tailored for individual molecules, alongside fundamental studies from the broad polymer science community, could facilitate design of such systems. Cover art designer: Joshua D. Moon View the article. ACS Macro Letters published several important papers on novel synthesis of naturally derived synthetic polysaccharides and glycopolymers. For example, Grinstaff and his colleagues have published a number of ACS Macro Letters on their polyamidosaccharides (PASs) over the years. PAS is a type of naturally derived synthetic polysaccharide, made .... Therussianbadger wife